Resonance Elastic Measurements

The correlation between the effective strain of a polymer chain and its absorption energy, established from direct absorption measurements on stretched polymer fibres allows an independent determination of the length of the repeat unit as a function of X via optical absorption measurements Data obtained by this method display a systematic deviation from the theoretical plot (Fig. 7) as do data derived from resonant Raman measurements . This indicates that the agreement between experimental data and predictions of the elastic strain (ES)-theory is fulfilled only... 

Perhaps the most unambiguous method is the measurement of the angular distribution of the resonance elastic scattering. For Z = 0 this is S5mimetric in the center of mass system. For / = 4= 0 but Ja= Ja= > the angular distribution is of the form... 

The Weissenbetg Rheogoniometer is well suited to research on homogeneous viscoelastic fluids and elastic melts. For oscillatory shear a second motor-drive mechanism is added. This allows the use of 60 frequencies in the range of 7.6 x 10 to 40 Hz at ampHtudes between 2 x 10 and 3 X 10 rad. An electronic circuit improves the precision of oscillatory measurements, particularly at frequencies neat the natural resonance frequency of the instmment itself (298). 

Pd4oCu4oP2o, Pd5oCu3oP2o, and Pd6oCu2oP20 alloys were measured by resonant ultrasound spectroscopy (RUS). In this technique, the spectrum of mechanical resonances for a parallelepiped sample is measured and compared with a theoretical spectrum calculated for a given set of elastic constants. The true set of elastic constants is calculated by a recursive regression method that matches the two spectra [28,29]. 

There is some disagreement in the literature as to the value of the (4He, H) elastic scattering cross section. Values differing by almost a factor of two have been reported, as reviewed by Paszti et al. (1986). The cross section is strongly non-Rutherford, but ab initio calculations have been reported that agree well with the trend of experimental data and could be used in simulation calculations (Tirira et al., 1990). The cross section for deuterium analysis has a resonance near a 4He+ energy of 2.15 MeV, which allows enhanced sensitivity. Detailed measurements of this cross section have been reported by Besenbacher et al. (1986). In practice, rather than calculate an experiment s calibration from first principles, calibration standards are usually used hydrogen-implanted silicon standard are the norm. 

C. J. Lewa and J. D. De Certaines, Viscoelastic property detection by elastic displacement NMR measurements, J. Magn. Reson. Imaging, 1996, 6, 652-656. 

The shear-mode acoustic wave sensor, when operated in liquids, measures mass accumulation in the form of a resonant frequency shift, and it measures viscous perturbations as shifts in both frequency and dissipation. The limits of device operation are purely rigid (elastic) or purely viscous interfaces. The addition of a purely rigid layer at the solid-liquid interface will result a frequency shift with no dissipation. The addition of a purely viscous layer will result in frequency and dissipation shifts, in opposite directions, where both of these shifts will be proportional to the square root of the liquid density-viscosity product v Pifti-... 

When one measures fluorescence spectra of a microsphere, a complication occurs that is not encountered in the study of bulk samples. That complication is the effect of elastic resonances on the inelastic scattering. Chew et al. (1976) predicted that the high internal electric field associated with morphological resonances leads to enhancement of fluorescence and Raman emissions, and Benner and his coworkers (1980) were among the first to observe morphological resonances associated with fluorescing molecules embedded in a microsphere. 

An analysis of the transfer function of this system can be made using the matrix method described by Okano et al. (1987). However, the stiffness of the rubber pieces is highly nonlinear. Okano et al. (1987) found that the measured transfer function does not fit theoretical predictions based on a constant stiffness. A nonlinear elastic behavior must be taken into account. Another problem with the metal-stack system is that the resonance frequency is around... 

These piezoelectric crystal oscillators are very accurate mass sensors because their resonant frequencies can be measured precisely with relatively simple electronic circuitry. For certain quartz crystals, the resonant frequency is inversely related to the crystal thickness. A crystal resonating at 5 megahertz is typically 300 micrometers thick. If material is coated or adsorbed on the crystal surface, the resonant frequency will change (decrease) in proportion to the amount of material added. The effect of adsorbed mass on the oscillator frequency varies according to the operational mode of the device. In any case, interpretation of mass via changes in frequency or amplitude assumes that the coated films are rigidly elastic and infinitesimally thin (that is, an extension of the crystal). 

Although QCM has originally been devised as a mass sensor for operation in vacuum or gas, it also appeared to be suitable for measurements of the mass and visco-elastic changes at a solid-liquid interface. That was possible due to elaboration of the dedicated oscillator circuitry [115]. The Sauerbrey Equation (2) was derived for resonator oscillations in vacuum. However, it also holds for solution measurements provided that (1) the deposited film is rigid and (2) it is evenly... 

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