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Replacement Reactions Involving Multidentate Ligands

There is no reason to believe that replacement of water by the donor groups of a chelating agent is fundamentally different from replacement when only unidentate ligands are involved. However, the multiplicity of steps may increase the difficulty in understanding the detailed mechanism, and mainly for this reason the simpler bidentate ligands have been most studied. [Pg.219]

Ligand Replacement Multidentate by Multidentate.—review of multidentate ligand exchange reactions and their application to analytical chranistry has appeared for systems involving egta and 4-(2-pyridylazo)resorcinol. ... [Pg.201]

Ligand Replacement Multidentate by Multidentate.—References to kinetic studies of reactions which involve simple replacement of multidentate ligands by other multidentate ligands are listed in Table 24. " Closely related investigations include an e.s.r, study of ligand-replacement reactions in the system [Cu(dtp)2HCu(dtp)(dtc)]-[Cu(dtc)2], for which rate constants and activation parameters are available, and a qualitative study of the yttrium(m)-hexafluoroacetylacetone-trifluoroacetylacetone system. ... [Pg.245]

See other pages where Replacement Reactions Involving Multidentate Ligands is mentioned: [Pg.219]    [Pg.219]    [Pg.221]    [Pg.223]    [Pg.219]    [Pg.219]    [Pg.221]    [Pg.223]    [Pg.73]    [Pg.190]    [Pg.2676]   


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