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Remote carboxyl groups synthesis

An 5n2 displacement of a caesium carboxylate on a remote mesylate group is used in an effective synthesis of / -zearaIenone. This compound has also been prepared by carbon-carbon bond formation using the displacement of a tosylate group by a protected cyanohydrin carbanion. The intramolecular coupling of a terminal vinyl iodide with an enone catalysed by PdCl2(CH3CN)2 has been used as a route to an unsaturated 16-membered macrolide. ... [Pg.140]


See other pages where Remote carboxyl groups synthesis is mentioned: [Pg.6]    [Pg.1149]    [Pg.1030]    [Pg.207]    [Pg.87]    [Pg.271]    [Pg.113]    [Pg.737]    [Pg.152]    [Pg.496]    [Pg.48]    [Pg.62]    [Pg.653]    [Pg.349]    [Pg.1710]   
See also in sourсe #XX -- [ Pg.3 ]

See also in sourсe #XX -- [ Pg.3 ]




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Carboxylate, synthesis

Carboxylic synthesis

Group syntheses

Remote

Remote carboxyl groups

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