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Relative reactivity of hydride-donor reducing agents

LIA1H4 Amine Alcohol Alcohol Alcohol Alcohol Amine Alcohol [Pg.203]

LiAlH[OC(CH3)3]3 Aldehyde Alcohol Alcohol Alcohol Aldehyde NR [Pg.203]

Hydride reduction of carboxylic acid derivatives, such as the conversion of esters to alcohols, involves elimination steps in addition to hydride transfer. [Pg.203]

Table 5.3. Relative Reactivity of Hydride-Donor Reducing Agents... Table 5.3. Relative Reactivity of Hydride-Donor Reducing Agents...
Relative reactivity of hydride-donor reducing agents... [Pg.819]

Reduction by hydrogen-atom donors involves free-radical intermediates. Tri- -butyltin hydride is the most prominent example of this type of reducing agent. It is able to reductively replace halogen by hydrogen in organic compounds. Mechanistic studies have indicated a free-radical chain mechanism. The order of reactivity for the haldes is RI > RBr > RCl > RF, which reflects the relative ease of the halogen-atom abstraction. [Pg.288]

See other pages where Relative reactivity of hydride-donor reducing agents is mentioned: [Pg.267]    [Pg.125]    [Pg.267]    [Pg.205]    [Pg.288]    [Pg.1043]    [Pg.1139]   


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Hydride agents

Hydride donors reactivity

Hydride reducing agents

Reactivators agents

Reactivity relative reactivities

Reduced reactivity

Reducing agent

Relative reactivities

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