Reforming adiabatic

Description Syngas preparation section. The feedstock is first preheated and sulfur compounds are removed in a desulfurizer (1). Steam is added, and the feedstock-steam mixture is preheated again. A part of the feed is reformed adiabatically in pre-reformer (2). The half of feedstock-steam mixture is distributed into catalyst tubes of the steam reformer (3) and the rest is sent to TEC s proprietary heat exchanger reformer, "TAF-X" (4), installed in parallel with (3) as the primary reforming. The heat required for TAF-X is supplied by the effluent stream of secondary reformer (5). Depending on plant capacity, the TAF-X (4) and/or the secondary reformer (5) can be eliminated. 

REF1 1+8.90 32.61+ primary reformer adiabatic interna, heat exchange 79-1+5 MW equilibrium reaction on the combustion side oxidation ratio about 1.1 reforming conditions known by measurements... 

Figure 3.9 Thermodynamic equilibrium gas composition and reformer adiabatic temperature versus air ratio (X) for gasoline reforming [7] feed temperatures were 400°C for air, 200°C for steam and 20°C for the fuel left, S/C = 0 right, S/C = 0.7.

Pre-Keformer A pre-reformer is based on the concept of shifting reforming duty away from the direct-fired reformer, thereby reducing the duty of the latter. The pre-reformer usually occurs at about 500°C inlet over an adiabatic fixed bed of special reforming catalyst, such as sulfated nickel, and uses heat recovered from the convection section of the reformer. The process may be attractive in case of plant retrofits to increase reforming capacity or in cases where the feedsock contains heavier components. 

ATR(l) [Autothermal reforming] A process for making CO-enriched syngas. It combines partial oxidation with adiabatic steam-reforming. Developed in the late 1950s for ammonia and methanol synthesis. Further developed in the 1990s by Haldor Topsoe. 

FCE tested a lab-scale carbonate fuel cell stack on a model diesel-like fuel (Exxsol) using an adiabatic pre-reformer to convert the liquid fuel to methane in 1991 to 1993. In 1995 and 1996, FCE verified a 32 kW MCFC stack operation on jet fuel (JP-8) and diesel (DF-2) in system inte-... 

Endothermic reactions can also be run with interstage heating. An example we have considered previously is the catalytic reforming of naphtha in petroleum refining, which is strongly endothermic. These reactors are adiabatic packed beds or moving beds (more on these in the next chapter) in which the reactant is preheated before each reactor stage. 

Typically, the prereforming process is performed in an adiabatic fixed-bed reactor upstream of the main reformer. In the pre-reformer, higher... 

The reforming process model is designed to predict the performance of many reactor configurations. The model can be run in four modes, combining adiabatic or isothermal reactors with recycle or single-pass (no recycle)... 

The accuracy of KINPTR over a wide spectrum of conditions and feedstocks will be demonstrated in this section. KINPTR predictions will be compared to a variety of R16H start-of-cycle and aging data from pilot plant and commercial reformers. Pilot plant data were obtained in both adiabatic and isothermal reactors. These predictions required complete reforming... 

Figure 17.13. Multibed catalytic reactors (a) adiabatic (b) interbed coldshot injection (c) shell and tube (d) built-in interbed heat exchanger (e) external interbed exchanger (f) autothermal shell, outside influent-effluent heat exchanger (g) multishell adiabatic reactor with interstage fired heaters (h) platinum-catalyst, fixed bed reformer for 5000 bpsd charge rate reactors 1 and 2 are 5.5 ft dia by 9.5 ft high and reactor 3 is 6.5 x 12.0 ft.

The source of nitrogen for the synthesis gas has always been air, either supplied directly from a liquid-air separation plant or by burning a small amount of the hydrogen with air in the H2 gas. The need for air separation plants has been eliminated in modern ammonia plants by use of secondary reforming, where residual methane from the primary reformer is adiabatically reformed with sufficient air to produce a 3 1 mole ratio hydrogen-nitrogen synthesis gas. 

Reforming in the CRG process occurs adiabatically at 450-550 C at pressures up to about 600 psig (41 atmospheres). The reactor is a vertical cylindrical pressure vessel containing a bed of the special high-nickel catalyst which is supported on a grid or on inert ceramic halls. The gas flow is downwards through the bed and distributors are provided at inlet and outlet. A layer of ceramic balls on top of the bed prevents disturbance of the catalyst by the entering gas. 

Fig. 1.3. Reactor system of a petroleum naphtha catalytic reforming plant. (The reactor is divided into three units each of which operates adiabatically, the heat required being supplied at intermediate stages via an external furnace)...

Catalytic reforming Pt, Pi-Re or Pt-Sn on acidified A1203 or on zeolite in matrix (adiabatic, fixed beds, or moving bed, with interstage heating)... 

A rigorous dusty gas model and two simplified models have been used to simulate industrial steam reformers and methanators. The basic principles for the solution of both the nonadiabatic steam reformer and the adiabatic methanator are given. The details of developing solution algorithms from the models are left to the reader as a serious and extensive project. 

Autothermal reforming reactor (ATR) is maintained under adiabatic conditions. There is no heat transfer from or to the reactor section during the reaction. The effect of S/C and O/C ratios on the net electric efficiency of the system with fuel cell has been calculated. The results are illustrated for different inlet temperatures (700° and 400°C) in Figures 7 and 8. A decrease of the S/C ratio decreases the efficiency. On the other hand, an... 

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