Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Reductive elimination involving two metal centers

Oxidative Addition and Reductive Elimination Involving Two Metal Centers... [Pg.303]

Several useful reviews have appeared. Mondal and Blake have collected thermochemical data on oxidative addition, Halpern has investigated the formation of C-H bonds by reductive elimination, while in a thought-provoking article on activation of C[5/ ]-X bonds, Chanon stresses the importance of electron transfer in oxidative addition (among other topics). In a discussion of oxidation addition and reductive elimination involving two metal centers, Halpem classifies and gives examples of three mechanisms whereby binuclear reductive elimination can occur concerted two center (77), concerted one center (78), and free-radical [(79)-(81)] reactions given in Scheme 6. [Pg.302]


See also in sourсe #XX -- [ Pg.280 ]




SEARCH



Metal center

Reduction centers

Two-center

© 2024 chempedia.info