Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Reduced self-energy

Alternately, by introducing the so-called reduced self-energy... [Pg.40]

If the solute were simply a collection of point charges surrounded by a continuous dielectric medium with the bulk dielectric constant of the solvent, the self-energy and the strength of charge-charge interactions in the solute would be reduced by a factor of . This is called dielectric screening. However, the solute itself occupies a finite volume, and solvent is excluded from this volume. This reduces the dielectric screening and is called... [Pg.80]

This way we take the quasi-particle energies which are described by an effective mass and a self-energy shift and solve the Schrodinger equation for the separable Yamaguchi potential. Separating the center of mass motion, with energy p2/2 from the relative motion, with reduced mass M M /(M +... [Pg.84]

The self-energy coefficient can be calculated simply from basic electrostatics. It depends on the size of the contact, and slightly on the shape, but assuming nearly circular contacts should be a good approximation. Since the electronic polarizability of the molecules will respond to the new situation, the electrostatic misfit energy is better approximated if we take this into account by reducing the energy by a portion, /dieiectric( °o = 2) = 0.4. Thus, we obtain the expression... [Pg.54]

We applied the generating functional approach to the periodic Anderson model. Calculation of the electron GFs gdd, 9ds, 9sd and gss reduces to calculation of only the d-electron GF. For this, an exact matrix equation was derived with the variational derivatives. Iterations with respect to the effective matrix element Aij(to) allow to construct a perturbation theory near the atomic limit. Along with the self-energy, the terminal part of the GF Q is very important. The first order correction for it describes the interaction of d-electrons with spin fluctuations. In the paramagnetic phase this term contains a logarithmic singularity near the Fermi-level and thus produces a Kondo-like resonance peak in the d-electron density of states. The spin susceptibility of d-electrons... [Pg.162]

The contributions that have been considered in order to obtain precise theoretical expressions for hydrogenic energy levels are as follows the Dirac eigenvalue with reduced mass, relativistic recoil, nuclear polarization, self energy, vacuum polarization, two-photon corrections, three-photon corrections, finite nuclear size, nuclear size correction to self energy and vacuum polarization, radiative-recoil corrections, and nucleus self energy. [Pg.149]

A recent calculation has substantially reduced the uncertainty of the contribution of the second-order one-photon electron self energy to the energy level of the IS state. In general, this contribution can be expressed as... [Pg.151]

The reducible part of AEgE)Wf, he-, the part of the diagram Fig. 1, (c) and (e), with the external state present in the propagator between the self-energy loop and the magnetic interaction, is given by [30,32]... [Pg.609]

AH matrices are of dimension 6Z and the harmonic propagator matrix G(0)(q m) is diagonal. The problem of calculating the phonon propagators thus reduces to the calculation of the self-energy matrices S(q ioif) that contain all anharmonic information. It is not difficult to demonstrate that the self-energy matrix is a Hermitian function of oif from which it follows that its analytic continuation in the complex frequency plane, in the neighborhood of the real axis, has the form... [Pg.158]

Major depression is a common psychiatric illness associated with significant morbidity [25]. The illness is usually episodic and manifests with a depressed mood reduced energy changes in appetite, sleep, and concentration and psychological symptoms, such as reduced self-esteem and suicidal ideation. As many as 10% of people may experience a depressive episode at some point in their lives, with women more commonly affected than men. Despite its frequency, more than half of the patients with this illness remain untreated [26]. Unfortunately, the longer the duration of the illness, the poorer the outcome, with an increased rate of recurrence [27]. Effective treatment for depression has been available for nearly two generations. Older medications, the tricyclic antidepressants and... [Pg.143]


See other pages where Reduced self-energy is mentioned: [Pg.178]    [Pg.207]    [Pg.80]    [Pg.314]    [Pg.211]    [Pg.135]    [Pg.205]    [Pg.45]    [Pg.44]    [Pg.178]    [Pg.480]    [Pg.26]    [Pg.348]    [Pg.213]    [Pg.2]    [Pg.128]    [Pg.51]    [Pg.334]    [Pg.151]    [Pg.382]    [Pg.613]    [Pg.801]    [Pg.54]    [Pg.151]    [Pg.382]    [Pg.613]    [Pg.801]    [Pg.567]    [Pg.91]    [Pg.114]    [Pg.80]    [Pg.64]    [Pg.249]    [Pg.179]    [Pg.86]    [Pg.125]   
See also in sourсe #XX -- [ Pg.40 ]




SEARCH



Energy reduced

Self-energy

Self-reducing

© 2024 chempedia.info