Redox reactions in liquid ammonia

The solvated electron in ammonia has a strong absorption band in the infrared region, and /Imax shifts from 1850 nm at 23 °C to 1410 nm at —75°C this is attributed to the effect of temperatiu-e on the orientation of the ammonia molecules in the first solvation shell [37], On the other hand, G(e am) = 0-32 pmol J remains constant over the same temperature range [37]. It is relatively straightforward, therefore, to study one-electron redox reactions in liquid ammonia by pulse radiolysis, but relatively few investigations have been made. 

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See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

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