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Redox and recognition processes, interplay

Redox and recognition processes, interplay between, 37, 315 Redox systems, organic, with multiple electrophores, electron storage and transfer in, 28, 1... [Pg.249]

The Interplay between Redox and Recognition Processes Models and Devices... [Pg.315]

Another example of a photoredox molecular switch is based on a ferrocene-ruthenium trisbipyridyl conjugate, in which the luminescent form 4 switches to the non-luminescent form 5 upon electrochemical oxidation (Figure 2/bottom)171. Biological systems exploit the interplay of redox and molecular recognition to regulate a wide variety of processes and transformations. In an attempt to mimic such redox systems, Deans et al. have reported a three-component, two-pole molecular switch, in which noncovalent molecular recognition can be controlled electrochemically. x Willner et al. have reported on their research activities in developing novel means to achieve reversible photostimulation of the activities of biomaterials (see Chapter 6).[91 Recently, we have shown that it is possible to switch the luminescence in benzodi-furan quinone 6 electrochemically. 101 The reduction in THF of the quinone moiety... [Pg.65]


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Recognition processes

Redox processes

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