Reactivity of Thiolate Complexes

Two thiolate complexes involved in oxygen atom transfer reactions. 

Hydrosulfido complexes, which contain M-SH groups, can react by an additional pathway unavailable to metal-thiolate complexes. Hydrosulfido complexes can react by cleavage of the S-H group to generate metal-sulfido complexes. The synthesis and reactivity of sulfido complexes are described in Qrapter 13 (metal-ligand multiple bonds). 

Transition-Metal-Silyl Complexes (Written with Dr.Tim A. Boebei) 

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