Reactions with Halides and Perhalogenated Compounds

Reactions of N2F4/NF2 with Halides and Perhalogenated Compounds. Underlined reactions are described in the text. 

7d CF3OSF4NF2 yield 14% other products COF2, SOF2, CF3OOCF3 

SFe no thermal reaction at 350 K [10] for irradiation with 2 to 3 MeV X-rays, only N2F4 decomposition [11] [10, 11] 

SF5CI SF5NF2, CI2 SF5CI N2F4 = 1.6 1 mixture irradiated with low-pressure Hg lamp for 120 h, yields SF5NF2 34%, CI2 30% [5] 

RJSF4R, Rf NF2, RfNF2, etc. Rf=Rf = C2F5i Rf = CF3, Rf = C2F5 reactions around 700°C and below 10 Torr high yields of Rf NF2, RfNF2 [12] 

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