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Reaction Mechanisms of Inorganic Nitrogen

Stedman, G. Reaction Mechanisms of Inorganic Nitrogen Compounds, Adv. Inorg. Chem. Radiochem. 22 [1979] 113/70,121. [Pg.38]

One of the most active fields in the study of mechanisms of reactions of inorganic nitrogen compounds is electrophilic nitrosation reactions. A very comprehensive monograph has been published on this topic, with a chapter devoted to nitrosation by inorganic nitrosyl complexes. The rate law for the most active nitrosating species normally takes the form of equation (24), and there has been... [Pg.113]

Fig. 6 The catalytic mechanism of the alkaline phosphatase reaction. The initial alkaline phosphatase (E)-catalyzed reaction consists of a substrate (DO-Pi) binding step, phosphate-moiety transfer to Ser-93 (in the TNAP sequence of its active site), and product alcohol (DOH) release. In the second step of the reaction, phosphate is released through hydrolysis of the covalent intermediate (E-Pi) and the non-covalent complex (E Pi) of the inorganic phosphate in the active site. In the presence of nitrogen-containing alcohol molecules (AOH), such as the buffer diethanolamine (DEA), phosphate is also released via a transphosphorylation reaction... Fig. 6 The catalytic mechanism of the alkaline phosphatase reaction. The initial alkaline phosphatase (E)-catalyzed reaction consists of a substrate (DO-Pi) binding step, phosphate-moiety transfer to Ser-93 (in the TNAP sequence of its active site), and product alcohol (DOH) release. In the second step of the reaction, phosphate is released through hydrolysis of the covalent intermediate (E-Pi) and the non-covalent complex (E Pi) of the inorganic phosphate in the active site. In the presence of nitrogen-containing alcohol molecules (AOH), such as the buffer diethanolamine (DEA), phosphate is also released via a transphosphorylation reaction...
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