Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Resolvent, Rayleigh-Schrodinger

In these expressions, fR is the Rayleigh-Schrodinger resolvent for the ground state, which can be written in sum-over-states form as... [Pg.17]

To make further progress, we introduce the Rayleigh-Schrodinger resolvent. [Pg.50]

The Rayleigh-Schrodinger resolvent In Rayleigh-Schrodinger perturbation theory the resolvent is defined by... [Pg.50]

An alternative approach, which we shall follow in this work, is to solve eqs. (4.145) and (4.146), which define the much simpler Brillouin-Wigner scheme, and introduce a correction term for the non-linear effects. The following identity relates the Brillouin-Wigner and the Rayleigh-Schrodinger resolvent denominators [17,18,74]... [Pg.170]

In order to develop the Rayleigh-Schrodinger perturbation expansion for the energy and the wave function, we define the resolvent... [Pg.41]

Elimination of the size-extensivity error in the MRBWCC theory was suggested by Hubac and Wilson [68]. The Brillouin-Wigner perturbation theory has been known notoriously as a method not furnishing size extensivity. There was therefore every reason to believe that the size-extensivity error in MR BWCCSD originated from the use of the Brillouin-Wigner type resolvent (15) instead of the Rayleigh-Schrodinger... [Pg.474]

Reduced Resolvent or the Almosf Inverse of MBPT Machinery Part 1 Energy Equation MBPT Machinery Part 2 Wave Function Equation BriUouin-Wigner Perturbation Theory Rayleigh-Schrodinger Perturbation Theory... [Pg.580]

The effective Hamiltonian (2.88) can be written in terms of the resolvent IRo for Rayleigh-Schrodinger perturbation theory as... [Pg.50]


See other pages where Resolvent, Rayleigh-Schrodinger is mentioned: [Pg.51]    [Pg.51]    [Pg.97]    [Pg.16]    [Pg.31]    [Pg.112]    [Pg.141]    [Pg.169]    [Pg.51]    [Pg.51]    [Pg.97]    [Pg.16]    [Pg.31]    [Pg.112]    [Pg.141]    [Pg.169]    [Pg.76]    [Pg.87]    [Pg.150]    [Pg.292]    [Pg.475]    [Pg.14]    [Pg.141]    [Pg.145]    [Pg.251]    [Pg.251]   
See also in sourсe #XX -- [ Pg.50 ]




SEARCH



Rayleigh-Schrodinger

© 2024 chempedia.info