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Random chain scission initiation first-order and disproportionation termination

2 Random chain scission initiation first-order and disproportionation termination [Pg.15]

SUMMARY OP DEPOLYMERIZATION BEHAVIOUR AT LONG AND SHORT ZIP LENGTHS [Pg.16]

Zip Termination length initial molecuhr weight distribution Weight loss rate Order Dependence of initial rate on molecular weight [Pg.16]

First-order Insensitive to initial dist. dAf, /I Early stages First-order only until x no longer 1/7 (early stages only) Independent [Pg.16]



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And disproportionation

Chain initiation

Chain initiators

Chain randomization

Chain scission

Chain scission chains

Chain termination

Chain terminators

Disproportionation, chain termination

First-order termination

Random chains

Random initiation

Random-chain scission

Terminal chains

Termination, disproportionation

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