Radicals sulfonylperoxy

Nitrobenzenesulfonylperoxy intermediate 51 had shown a larger oxidizing ability towards olefins compared with the 4-nitrobenzenesulfonylperoxy intermediate. When 2-nitrobenzenesulfonyl chloride reacts with 02" at low temperature (—20 to —35°C) in CH3CN, the corresponding sulfonylperoxy radical 51 or anion 52 is generated. The radical character of the sulfonylperoxy intermediate 51 was further confirmed by the electrophilic oxidizing nature of a 2-nitrobenzenesulfonyl chloride/KOi mixture. 

Nitrobenzene chloride, sulfonylperoxy radical reactions, 1035, 1036 2-Nitrobenzenesulfinylperoxy intermediate, superoxide reactions, 1034 Nitrogen-containing compound oxidation bis(trimethylsilyl) peroxide reactions, 802-3, 804 dioxiranes, 1151-5 primary aromatic amines, 1151 A-oxidation, 531-8, 539 Nitrohpids, hpid hydroperoxides, 952-4 Nitronate ions, dioxirane oxidation, 1152-3 Nitrosation, malondialdehyde, 667 Nitroso compounds, spin trapping, 664 Nitrotyrosine, peroxynitiite determination, 740-1... 

C-H bond unreactive to insertion, 1160 dioxirane oxidation, 1156 Sulfonic acids, C-H bond unreactive to insertion, 1160 Sulfonyl endoperoxides parasiticidal activity, 1309 synthesis, 1306-9, 1332 Sulfonyl peroxides, 1001-2, 1004-7 Sulfonylperoxy radical, superoxide reactions, 1035-9 Sulfoxidation... 

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