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Racemizations of Alkyl Groups in Cobaloxime Complex Crystals

Racemizations of Alkyl Groups in Cobaloxime Complex Crystals [Pg.19]

Keywords Photo-racemization Reaction rate Racemic-to-chiral transformation Anti-to-syn transformation Neutron diffraction [Pg.19]


Recently we found that the chiral alkyl group bonded to the cobalt atom in a cobaloxime complex crystal is almost (82%) inverted to the opposite configuration only by photoirradiation [12]. In this chapter we describe the processes of the racemic-to-chiral transformation and also the chirality inversion in the... [Pg.533]


See other pages where Racemizations of Alkyl Groups in Cobaloxime Complex Crystals is mentioned: [Pg.19]    [Pg.206]   


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Alkyl complexes

Alkylated cobaloximes

Alkylation complex

Alkylations complexes

Cobaloxim

Cobaloxim complexes

Cobaloxime alkylated

Cobaloxime complex

Cobaloximes

Complexes of Group

Crystals of complexes

In racemization

Racemic complex

Racemic crystals

Racemization groups

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