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Quinoxaline cyanates

QUINOXALINE CYANATES, ISOCYANATES, THIOCYANATES, ISOTHIOCYANATES, AND NITRONES... [Pg.356]

There is virtually no recent literature on quinoxaline cyanates or isocyanates, and most of what little there is on quinoxaline thiocyanates, isothiocyanates, or nitrones has been covered already the preparation of thiocyanatoquinoxalines from halogenoquinoxalines (Section 4.4.1) the conversion of the thiocyanatoquinoxalines into alkoxyquinoxalines (Section 4.4.1), into quinoxalinethiones (Section... [Pg.356]

These major routes to quinoxalmecarbonitriles have been covered already by primary synthesis (Chapter 1), by cyanalysis of halogenoquinoxalines (Section 3.2.5), by deoxidative cyanation of quinoxaline N-oxides (Section 4.6.2.2), by cyanolysis of nitroquinoxalines (Section 6.1.2.2), from primary quinoxalina-mines by a Sandmeyer-type reaction (Section 6.3.2.3), from quaternary ammonio-quinoxalines with cyanide ion (Section 6.3.2.4), and by dehydration of quinoxalinecarboxamides (Section 7.4.2). Those remaining preparative routes that have been used recently are illustrated in the following examples. [Pg.342]

The iV-( -nitrophcnyl)pipcrazinc-2-carbonitrilc 251 (Y = NBOC) was reductively cyclized to the tricyclic /V-oxides 252 (Y = NBOC) either by catalytic hydrogenation, or by electrochemical reduction. Electrochemical reduction gave lower yield. Compounds 251 were prepared by electrochemical cyanation of the iV-(o-nitrophenyl)piperazine 250. The jV-oxides 252 were further hydrogenated to the 2,3,4,4 ,5,6-hexahydro-l//-pyrazino[l,2- ]quinoxaline 253 (Y = NBOC) (Scheme 46) <2001EJ0987>. [Pg.292]

Quinoxaline iV-oxide is cyanated with potassium cyanide and potassium hexacyanofer-rate(III) in protic solvents (water or ethanol) in one step to yield quinoxaline-2-carbonitrile 1-oxide in 30% yield. ... [Pg.234]


See other pages where Quinoxaline cyanates is mentioned: [Pg.358]    [Pg.357]    [Pg.358]    [Pg.357]    [Pg.339]    [Pg.279]    [Pg.255]    [Pg.339]    [Pg.250]    [Pg.418]    [Pg.588]    [Pg.393]   
See also in sourсe #XX -- [ Pg.356 ]

See also in sourсe #XX -- [ Pg.356 ]




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