Quinolinium fluorochromate, oxidation with

The kinetics of oxidation of allyl alcohol with quinolinium fluorochromate have been studied.11 This reagent has also been used to oxidize benzyl alcohols the activation enthalpies and entropies obtained for the substituted derivatives are linearly related, and a Hammett relationship (p = —1.04 0.08) is obeyed.12... [Pg.180]

Oxidation of several primary aliphatic alcohols with potassium dichromate, pyri-dinium dichromate, quinolinium dichromate (QDC), imidazolium dichromate, nico-tinium dichromate, isonicotinium dichromate, pyridinium fluorochromate (PFC), quinolinium fluorochromate, imidazolium fluorochromate, pyridinium chlorochromate (PCC), quinolinium chlorochromate (QCC), and pyridinium bromochromate (PBC), in aqueous acetic acid and in the presence of perchloric acid, showed similar kinetics. The values of the reaction constants did not differ significantly, indicating operation of a common mechanism.1... [Pg.85]