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Quadricyclanes pyrolysis

Molecule 2 is of considerable theoretical interest.24 At the time of our success in generating 2 by flash pyrolysis of quadricyclane derivative 421 in combination... [Pg.118]

Both quadricyclane and norbornadiene are high-energy isomers of C7H8, and it is interesting to compare their thermal behavior. Figures 4.5 and 4.6 show the pyrolysis breakdown behavior for norbornadiene and quadricyclane, respectively, extracted as described above. As shown, norbornadiene (NBD) is stable on the available time scale for temperatures up to 600 K. (The small apparent decrease in NBD contribution in the 400-600 K range is within the uncertainty of the fitting process — no product species are observed.) Above 600 K decomposition... [Pg.62]

Figure 4.5 Pyrolysis breakdown be- Figure 4.6 Pyrolysis breakdown behav-havior for norbornadiene 1 — NBD 2 — lor for quadricyclane 1 — QC 2 — CsHe TOL and 3 — CsHe 3 — TOL and 4 — NBD... Figure 4.5 Pyrolysis breakdown be- Figure 4.6 Pyrolysis breakdown behav-havior for norbornadiene 1 — NBD 2 — lor for quadricyclane 1 — QC 2 — CsHe TOL and 3 — CsHe 3 — TOL and 4 — NBD...
See other pages where Quadricyclanes pyrolysis is mentioned: [Pg.61]    [Pg.70]    [Pg.88]    [Pg.97]    [Pg.364]    [Pg.60]    [Pg.183]    [Pg.341]    [Pg.195]    [Pg.302]   
See also in sourсe #XX -- [ Pg.96 , Pg.431 ]



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Quadricyclane

Quadricyclanes

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