Pyrolysis continued through

Commercially and industrially most important, ketene itself, H2C—C—O, is produced by pyrolysis of acetic acid [64-19-7]. In this process, high quahty acetic acid is evaporated and the vapor passed continuously through a radiant coil under reduced pressure at 740—760°C. 

For the preparative formation of pyrolysis products it was necessary to provide an arrangement in which the gases involved flowed continually through the apparatus, the lingering time of these gases in the reaction zone lasting approximately one minute. The results are shown in Table 4 [18, 19, 20]. 

The majority of the cyanuric acid produced commercially is made via pyrolysis of urea [57-13-6] (mp 135°C) primarily employing either directiy or indirectly fired stainless steel rotary kilns. Small amounts of CA are produced by pyrolysis of urea in stirred batch or continuous reactors, over molten tin, or in sulfolane. The feed to the kilns can be either urea soHd, melt, or aqueous solution. Since conversion of urea to CA is endothermic and goes through a plastic stage, heat and mass transport are important process considerations. The kiln operates under slight vacuum. Air is drawn into the kiln to avoid explosive concentrations of ammonia (15—27 mol %). 

Continuous production of fullerenes was possible by pyrolysis of acetylene vapor in a radio-frequency induction heated cylinder of glassy polymeric carbon having multiple holes through which the gas mixture passes [44]. Fullerene production is seen at temperatures not exceeding 1500 K. The yield of fullerenes, however, generated by this method is less than 1%. A more efficient synthesis (up to 4.1% yield) was carried out in an inductively coupled radio-frequency thermal plasma reactor [45]. 

Studies of 0/ 0 isotope variations in several vascular plant species, mosses and environmental surface bog water from temperate peat bogs (Switzerland) used as climatic archives for paleoclimatic reconstruction were reported by Menot-Combes et 8 0-values in organic material were determined by the online continuous flow method after sample pyrolysis at 1080 °C in the presence of glassy carbon in a Carlo-Erba elemental analyzer. The gases obtained (CO, N2 and H2O) were separated by passing them through a water trap and a GC column in a helium carrier gas. The isotope composition of CO was measured with a VG Prism II isotope ratio mass spectrometer relative to the VSMOW isotope standard. The overall analytical uncertainty is 0.08%o for water 8 0-values." ... 

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