Pyrite topologies

Fig. 12 Biased DCLs consisting of persistent capsule receptors self-assembled from 23 and MS04 (M = Mg2+, Zn2+, Cd2+, Co2+, Mn2+) or Li2S04 into crystalline frameworks with NaCl and pyrite topologies, respectively...

More recent studies indicated that the capsules also persist in crystalline frameworks self-assembled from completely different cations [47]. Thus, when 23 was crystallized with Li2S04, similar S04(23)22 capsules formed, linked this time by Li(H20)+ cations into a cubic coordination framework with pyrite topology (Fig. 12). Once again, the capsules preserved their structures in the presence of... 

TOPOLOGICAL PROPERTIES AND ELECTRONIC STRUCTURES OF COMPOUNDS WITH PYRITE-TYPE CRYSTAL STRUCTURES... 

Inorganic. - Aray et correlated the topology of p of pyrite-type transition metal sulfides with their catalytic activity in hydrodesulfurization. The most active catalysts are characterized by intermediate values at the M-S BCP. This result supports the consistency of transition-metal-sulfide-catalysed hydrodesulfurization with the Sabatier principle. 

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