Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Pyridylphosphole ligands

The pyridylphosphole ligands possess two coordination centers with different stereoelectronic properties which, in accordance with the Pearson antisymbiotic effect [16c], allows the control the orientation of a second chelating ligand in the... [Pg.303]

One key property of pyridylphosphole ligands is their heteroditopic nature. They possess two coordination centers with different stereo-electronic properties, which, in accordance with Pearson s antisymbiotic effect [42a], can control the orientation of a second chelating ligand in the coordination sphere of a square-planar d8-metal center [42b]. This property has been exploited in order to control the in-plane parallel arrangement of ID-dipolar chromophores [42d]. Phospholes... [Pg.135]

Hay C, Sauthier M, Deborde V, Hissler M, Toupet L, Reau R (2002) A bridging ligand featuring terminal 2-pyridylphosphole moieties synthesis, optical properties and Ru(II)-complex. J Organomet Chem 643-644 494... [Pg.371]


See other pages where Pyridylphosphole ligands is mentioned: [Pg.142]    [Pg.150]    [Pg.305]    [Pg.135]    [Pg.1135]    [Pg.1137]    [Pg.12]    [Pg.485]    [Pg.353]    [Pg.368]   
See also in sourсe #XX -- [ Pg.135 ]




SEARCH



Pyridylphospholes

© 2024 chempedia.info