Pseudoplastic Viscosity profiles

Pseudoplastic and thixotropic cleaning compositions with specifically defined viscosity profile... 

As discussed earlier, LADDs are complex, multicomponent mixtures consisting of both organic and inorganic compounds dispersed in a liquid matrix. Such compositions can exhibit a broad range of rheological characteristics from simple Newtonian to complex pseudoplastic flow. Shown in Figure 9.6 and Figure 9.7 are flow and viscosity profiles of Newtonian and non-Newtonian fluids as a function of applied shear rate. A number of mathematical models have been proposed [76] to describe the flow characteristics of various systems. These equations are called constitutive equations and are used to predict flow behavior in complex systems. 

Based on viscosity of the samples, the flow of samples is broadly classified into three categories, namely, Newtonian, time independent non-Newtonian and time dependent non-Newtonian. Newtonian fluids show shear stress independent constant viscosity profile where as non-Newtonian fluids show a viscosity profile, which is dependent on the shear force and time. In time independent non-Newtonian fluids, the shear stress does not vary proportionally to the shear rate. The time independent non-Newtonian fluids show mainly three types of flow. A decreasing viscosity with an increase of shear rate is called shear thinning or pseudoplastic flow (Figure 46.12a). An increasing viscosity with an increase of shear rate is called shear thickening or dilatant flow. Some fluids need application of certain amount of force before any flow is induced that are known as Bingham plastics. 

Before the viscosity can be calculated from capillary data, as mentioned above, the apparent shear rate, 7 , must be corrected for the effect of the pseudoplastic nature of the polymer on the velocity profile. The calculation can be made only after a model has been adopted that relates shear stress and shear rate for this concept of a pseudoplastic shear-thinning material. The model choice is a philosophical question [11] after rheologlsts tried numerous models, there are in general two simple models that have withstood substantial testing when the predictions are compared with experimental data [1]. The first Is ... 

The velocity profiles of pseudoplastic non-Newtonian fluids (Fig. 8) in laminar flow deviate from the Newtonian parabola in the same way as the velocity profile of Newtonian liquids changes when heat is being transferred to them (M4, p. 229), since in both cases the viscosity of the fluid is lower at the wall than at the center of the tube. For the Newtonian... 

The pseudoplasticity, the salt tolerance and the relatively favorable viscosity-temperature profiles may make these copolymers of potential interest in oil recovery or drilling applications. 

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