Proton loading sites

Pumping mechanism, cytochrome c oxidase basic physical principle, 79—80 Coulomb machine gun, 80 le/lH-t pumping ratio, 78 membrane potential, 83—84 pK quantum mechanics/molecular mechanics calculations, 84 proton collecting antenna and proton conducting channels, 83 proton loading site (PLS), 80, 82—83 pump element, heme a, 78 water chains, 82... 

A remarkable application of phosphines by Grey and coworkers for acid site characterization is the use of diphosphines with alkyl chain spacers of different length between the phosphine moieties. Based on careful NMR analysis and appropriate loading levels with diphosphines, the Al distribution can be determined [223, 224], The idea behind this tool is that the phosphine groups will be proto-nated, when they are close to an acid site in the zeolite structure. Protonation of both phosphine groups in one probe molecule will only occur, when the distance between the two acid sites is compatible with the molecular dimension of the diphosphine. 

The spurred impetus has been given to developing non pollutant vehicles, and consequently, the clean cars driven by the fuel cells loading proton exchange membranes (PEMFC), which based upon Nafion, have been surprisingly developed. A promising less pollutant and economical system is also expected, which will be the on site cogeneration system of electric power and the hot water supply with use of fuel cells combined with city gas pipe-lines. 

The active site concentration on the organochromium catalysts may be higher than that of the oxide catalysts. The activity usually assumes a more linear increase with chromium loading than on the oxide catalysts, at least up to 2% Cr. Yermakov and Zakharov, studying allyl-Cr(III)/silica catalysts, stopped the polymerization with radioactive methanol, and found that the kill mechanism is different from that on the oxide catalysts (59). The proton of the methanol, and not the alkoxide, became attached to the polymer. This suggests a polarity opposite to that of the oxide catalysts, with the site being more positive than the chain. 

The function of a proton-conducting ionomer such as Nafion in the catalyst layer is to provide an ionic path for proton migration from the membrane to the reaction site at the catalyst surface. Therefore, the content of the proton-conducting ionomer in the catalyst layer will greatly influence the transport of protons to the catalyst sites. The impedance spectra of fuel cells with different Nafion loadings in the catalyst layers of both the cathode and the anode at OCV were compared by... 

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