Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Propene addition

When initiation takes place with an un-symmetrical monomer such as 2-methyl-propene, addition occurs to the double bond... [Pg.665]

MA(JV, A -Tetramethylethylenediamine (TMEDA) is not inert toward alkyllithiums as the latter can abstract a proton from one of the methyl groups. Under modified conditions (p. 131), P-elimination takes place producing dimethylvinylamine and lithium dimethylamide instead. If the reaction is accomplished in the presence of propene, addition of the lithium amide restores an elimination-mediating base. ... [Pg.125]

CHjiCH-CN. Volatile liquid b.p. 78"C. Manufactured by the catalytic dehydration of ethylene cyanhydrin, by the addition of hydrogen cyanide to ethyne in the presence of CuCI or the reaction of propene, ammonia and air in the presence of a molybdenum-based catalyst. [Pg.329]

The 2-alken-4-ynylamine analogues (A. Stiitz, 1987) are best synthesized by Grignard-type additions of lithium acetylides to propenal and either... [Pg.303]

Kharasch s earliest studies in this area were carried out in collab oration with graduate student Frank R Mayo Mayo performed over 400 experi ments in which allyl bromide (3 bromo 1 propene) was treated with hydrogen bromide under a variety of conditions and determined the distribution of the normal and abnormal products formed during the reaction What two prod ucts were formed Which is the product of addition in accordance with Markovmkovs rule Which one corresponds to addition opposite to the rule ... [Pg.243]

FIGURE 6 8 Mechanism of addition of sulfuric acid to propene... [Pg.246]

Markovmkov s rule is obeyed because the mechanism of sulfuric acid addition to alkenes illustrated for the case of propene m Figure 6 8 is analogous to that described earlier for the electrophilic addition of hydrogen halides... [Pg.246]

The combination of sulfuric acid addition to propene followed by hydrolysis of the resulting isopropyl hydrogen sulfate is the major method by which over 10 lb of isopropyl alcohol is prepared each year m the United States... [Pg.246]

In this example addition to the double bond of an alkene converted an achiral mol ecule to a chiral one The general term for a structural feature the alteration of which introduces a chirality center m a molecule is prochiral A chirality center is introduced when the double bond of propene reacts with a peroxy acid The double bond is a prochi ral structural unit and we speak of the top and bottom faces of the double bond as prochiral faces Because attack at one prochiral face gives the enantiomer of the com pound formed by attack at the other face we classify the relationship between the two faces as enantiotopic... [Pg.297]

Isoxazole-3-carbaldehyde has been obtained as a minor product from the reaction of acetylene with a mixture of nitric oxide and nitrogen dioxide (61JOC2976). Although 3-aryl-4-formylisoxazoles have been synthesized in good yields from the reaction of benzonitrile Af-oxides with 3-(dimethylamino)-2-propen-l-one (71S433), the parent member of the series, isoxazole-4-carbaldehyde, has never been reported. It may possibly be obtained by the addition of fulminic acid to 3-(dimethylamino)-2-propen-l-one. [Pg.84]

Methyl-2-propen-l-ol, purchased from Aldrich Chemical Company, was distilled from anhydrous potassium carbonate. It was added directly to the n-butyllithium solution using a long needle. The checkers quickly replaced the pressure-equalizing dropping funnel with a serum cap to carry out this addition. The funnel was fitted to a small dry flask to prevent the introduction of moisture during the addition period and replaced on the reaction flask immediately afterwards. [Pg.61]

Fluorobenzene is readily alkylated with alkenes in the presence of protic acids, however, the isomenc purity of the product is poor, and polysubstitution can result Thus, propene and sulfuric acid alkylate fluorobenzene at 20 C to yield a 45 55 ortho/para ratio of the inonoalkyl product m addition to di- and triiso propylfluorobenzene [i5] The reaction of benzene and trifluoropropene at 25 °C in HF-BF3 gives a mixture of mono-, bis-, and tns(3,3,3-trifluoropropyl)ben zene [72, 75] (equation 12)... [Pg.412]

At room temperature, base-catalyzed addition of thiophenol to phenyl trifluo-romethyl acetylene gives exclusively (Z)-3-phenyl-3-phenylthio-l,1,1-tnfluoro-propene. At 150 °C, the predominant isomer is the E isomer (64%), with 23% of the Z isomer and 13% of the other two regioisomers [4] (equation 5). [Pg.758]

Is the electrophilic addition of hydrogen chloride to 2-methyl-propene the reverse of the El or the E2 elimination reaction of fe/t-butyl chloride ... [Pg.250]

Dimethylborane+propene Cl depicts the transition state for addition of dimethylborane onto the terminal alkene carbon of propene. Examine and describe the vibration with the imaginary frequency. Which bonds stretch and compress the most What simultaneous changes in bonding are implied by these motions Simultaneously display the highest-occupied molecular orbital (HOMO) of propene and the lowest-unoccupied molecular orbital (LUMO) of dimethylborane. Is the overall geometry of the transition state consistent with constructive overlap between the two Explain. [Pg.112]

Obtain the energies of propene, dimethylborane, and 1-propyldimethyl borane, and calculate AH n for dimethylborane addition. Is this reaction exothermic or endothermic Use this result and the Hammond Postulate to predict whether the transition state will be more reactant like or more product like . Compare the geometry of the transition state to that of the reactants and products. Does the Hammond Postulate correctly anticipate the structure of the transition state Explain. [Pg.112]

Dimethylborane+propene C2 and 2-propyldimethyl borane depict the regioisomeric transition state and addition product. Calculate the energies of these species relative to those of the alternative transition state and product. Given these energy differences, and the experimental observation that this addition is almost completely selective for the anti-Markovnikov product, does it appear that this reaction is under kinetic or thermodynamic control Explain. [Pg.112]


See other pages where Propene addition is mentioned: [Pg.253]    [Pg.112]    [Pg.68]    [Pg.398]    [Pg.535]    [Pg.262]    [Pg.253]    [Pg.112]    [Pg.68]    [Pg.398]    [Pg.535]    [Pg.262]    [Pg.164]    [Pg.143]    [Pg.199]    [Pg.180]    [Pg.439]    [Pg.317]    [Pg.209]    [Pg.83]    [Pg.36]    [Pg.41]    [Pg.175]    [Pg.175]    [Pg.54]    [Pg.995]    [Pg.243]    [Pg.104]   
See also in sourсe #XX -- [ Pg.2 , Pg.41 ]




SEARCH



2- methyl-1-chloro-1-propene, addition

Addition of Organic Acids to Propene

Additions 1 -methoxy-2-methyl-1 - propene

Propene addition of sulfuric acid

Propene radical addition

© 2024 chempedia.info