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Principle of Nonperfect Synchronization PNS

This year marks the 25th anniversary of the principle of nonperfect synchronization (PNS) it was introduced in 19851 as the principle of imperfect synchronization (PIS) but in later papers and reviews2 4 the name was changed due to the awkwardness of the acronym PIS. The foundations of the PNS rest mainly on a marriage between two fundamental concepts of physical organic chemistry, i.e., the concept of intrinsic barriers and that of transition state imbalances. [Pg.223]

On the basis of equation 5, we (8) formulated the principle of nonperfect synchronization (PNS)2 as follows A product-stabilizing factor (8 log K/ > 0) always lowers k0 if it develops late (otf< P) but increases k0 if it develops early... [Pg.120]

See other pages where Principle of Nonperfect Synchronization PNS is mentioned: [Pg.169]    [Pg.409]    [Pg.828]    [Pg.907]    [Pg.907]    [Pg.409]    [Pg.169]    [Pg.409]    [Pg.828]    [Pg.907]    [Pg.907]    [Pg.409]    [Pg.380]   
See also in sourсe #XX -- [ Pg.409 ]

See also in sourсe #XX -- [ Pg.409 ]



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