Primitive mantle major element composition

Major-element compositions (weight ratios of Mg/Si and Al/Si) for mantle rocks (peridotites) and estimates of the primitive mantle composition of the Earth compared with various groups of chondrites and the Sun. No mixture of chondrite types provides an exact match to the primitive mantle composition, although some carbonaceous chondrites provide the closest match. Modified from Righter et al. (2006). 

Major element composition of the Earth s primitive mantle... 

Calculating the composition of the Archaean mantle is a task which has occupied geochemists for some decades. It is not a trivial task because the nature of the Archaean mantle is that it was constantly changing in composition. However, estimates of the primitive mantle composition, also known as the composition of the BSE - the mantle as it was after the core has been extracted but before the continents were formed - are given at various points in this chapter, as follows estimates of the major element composition of the primitive mantle are given in Table 3.1 the composition of the Archaean subcontinental lithosphere in Table 3.4 the trace element composition of the primitive mantle in... 

Figure 6 Major-element oxides (wt.%) versus FeO as a function of pressure (GPa) and degree of batch melt extraction (sources the 1 GPa and 2 GPa trends are based on the Kinzler and Grove (1992a, 1993) model for melting of primitive mantle of McDonough and Sun (1995) (composition 1, Table 1), and the trends at higher pressures are based on the data of Walter (1998) for melting of fertile peridotite KR4003).

Figure 10 shows major-element oxides versus Mg for off-craton and oceanic mantle, as well as some estimated compositions for primitive mantle (Table 1). As expected from the normative plots, the two sets of mantle compositions have distinct trends for all oxides. Previous models for primitive upper mantle have a range in Mg from 89 to 90, and Figures 9 and 10 show that the oceanic and off-craton trends also converge within this range. Assuming that the off-craton and abyssal mantle trends are due primarily to melt extraction from a common protolith, then the intersection of the trends should provide a good estimate for the composition of fertile upper mantle for major elements. 

Figure 10 Major-element oxides versus Mg for the off-craton mantle subset (shaded circles) and reconstructed abyssal peridotite compositions (open circles). Primitive mantle compositions from Table 2 are also shown with symbols as in Figure 9.

Developing a model for the composition of the Earth and its major reservoirs can be established in a four-step process. The first involves estimating the composition of the silicate Earth (or primitive mantle, which includes the crust plus mantle after core formation). The second step involves defining a volatility curve for the planet, based on the abundances of the moderately volatile and highly volatile lithophile elements in the silicate Earth, assuming that none have been sequestered into the core (i.e., they are truly lithophile). The third step entails calculating a bulk Earth composition using the planetary volatility curve established in step two, chemical data for chondrites, and... 

As refractory lithophile elements, the REE play an important role in constraining the overall composition and history of the silicate fraction of planets, which for the terrestrial planets is also termed their primitive mantle (equivalent to the present-day crust plus mantle). Since there is no evidence for significant planetary-scale fractionation of refractory elements during the assembly and differentiation of planetary bodies, it is widely accepted that the primitive mantles of terrestrial planets and moon possess chondritic proportions of the REE. As such, the absolute concentrations of REE (and other refractory elements) in primitive mantles provide an important constraint on the proportions of volatile elements to refractory elements and on the oxidation state (i.e., metal/silicate ratio) of the body. To date, the only major planetary bodies for which REE data are directly available are the Earth, Moon, and Mars, and Taylor and McLennan" recently reviewed these data. 

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