Presentation of voltammetric data

Cyclic voltammograms can be presented in an alternative format to that shown in Fig. 5 by using a time rather than potential axis, as shown in Fig. 8. The equivalent parameters in steady-state voltammetric techniques are related to a hydrodynamic parameter (e.g. flow-rate, rotation speed, ultrasonic power) or a geometric parameter (e.g. electrode radius in microdisc voltammetry). 

---

The two major classes of voltammetric technique 4 Evaluation of reaction mechanisms 6 General concepts of voltammetry 6 Electrodes roles and experimental considerations 8 The overall electrochemical cell experimental considerations 12 Presentation of voltammetric data 14 Faradaic and non-Faradaic currents 15 Electrode processes 17 Electron transfer 22 Homogeneous chemical kinetics 22 Electrochemical and chemical reversibility 25 Cyclic voltammetry 27 A basic description 27 Simple electron-transfer processes 29 Mechanistic examples 35... 

---