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Preorganized binding site

In order to build better hosts which have preorganized binding sites. Cram and co-workers have prepared hemispherands [50] and spherands [51],... [Pg.93]

Molecular recognition mainly deals with selective complexation of the host-guest type. In order to achieve selectivity, a host molecule must be rigid so as to allow a preorganized binding site which is complementary in size and polarity to a particular guest [1]. Selective complexation itself is an important object, but more than that. It plays an essential role in the various aspects of supramolecular functions [2]. [Pg.17]

Molecular mechanics and dynamics calculations have shown that the preorganization of 21 for cation or anion binding and recognition results from its high connectivity and its preformed cavity with converging binding sites and fairly fixed size [1.45,2.36b]. [Pg.25]

See other pages where Preorganized binding site is mentioned: [Pg.180]    [Pg.109]    [Pg.8]    [Pg.2434]    [Pg.2433]    [Pg.172]    [Pg.1292]    [Pg.1256]    [Pg.3280]    [Pg.369]    [Pg.431]    [Pg.24]    [Pg.27]    [Pg.129]    [Pg.207]    [Pg.180]    [Pg.109]    [Pg.8]    [Pg.2434]    [Pg.2433]    [Pg.172]    [Pg.1292]    [Pg.1256]    [Pg.3280]    [Pg.369]    [Pg.431]    [Pg.24]    [Pg.27]    [Pg.129]    [Pg.207]    [Pg.176]    [Pg.176]    [Pg.123]    [Pg.304]    [Pg.122]    [Pg.185]    [Pg.83]    [Pg.87]    [Pg.292]    [Pg.186]    [Pg.58]    [Pg.57]    [Pg.570]    [Pg.132]    [Pg.57]    [Pg.306]    [Pg.310]    [Pg.105]    [Pg.110]    [Pg.12]    [Pg.18]    [Pg.2]    [Pg.214]    [Pg.936]    [Pg.176]    [Pg.176]    [Pg.185]    [Pg.139]    [Pg.54]    [Pg.306]    [Pg.310]    [Pg.221]   
See also in sourсe #XX -- [ Pg.109 ]



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