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Positive-negative polarity

It has been suggested that the linearization error can be even further reduced by making four measurements two sets of positive-negative polarizations at two different polarization values. However, the use of the three-point technique may be more advantageous as long as multiple measurements are carried out. [Pg.157]

FIGURE 4 3 Adipole-dipole attractive force Two molecules of a polar sub stance associate so that the positively polarized region of one and the negatively polarized region of the other attract each other... [Pg.148]

Induced dipole/induced dipole forces are the only intermolecular attractive forces available to nonpolar molecules such as alkanes In addition to these forces polar molecules engage m dipole-dipole and dipole/mduced dipole attractions The dipole-dipole attractive force is easiest to visualize and is illustrated m Figure 4 3 Two molecules of a polar substance experience a mutual attraction between the positively polarized region of one molecule and the negatively polarized region of the other As its name implies the dipole/induced dipole force combines features of both the induced dipole/mduced dipole and dipole-dipole attractive forces A polar region of one mole cule alters the electron distribution m a nonpolar region of another m a direction that produces an attractive force between them... [Pg.148]

Overall the reaction is classified as an addition Water adds to the carbonyl group Hydrogen becomes bonded to the negatively polarized carbonyl oxygen hydroxyl to the positively polarized carbon... [Pg.713]

Section 17 2 The carbonyl carbon is sp hybridized and it and the atoms attached to It are coplanar Aldehydes and ketones are polar molecules Nucleophiles attack C=0 at carbon (positively polarized) and electrophiles especially protons attack oxygen (negatively polarized)... [Pg.742]

The system for shielded-metal arc welding, shown in Figure 2a, is the simplest system. It consists of the power source, electrode and holder, the base metal, and the electrical cables or leads. When the arc is stmck, a complete electrical circuit is provided. With d-c welding, the electrode maybe either negative (straight polarity) or positive (reverse polarity). Shielded metal arc welding is only used manually. [Pg.343]

A limited number of minus-x orientation samples were impact loaded in the vicinity of the Hugoniot elastic limit at stresses from 5.9 to 6.7 GPa. The principal observation of these experiments was that positive currents were observed from negative polarity disks when a stress of 5.9 GPa was exceeded. Such an observation confirms that quartz responds as predicted by the model, and that the elastic limit is in the vicinity of 6 GPa. [Pg.102]

There is a pronounced tendency for boron to become bonded to the less substituted carbon of the double bond. Thus, the hydrogen atoms of diborane add to C-2 of 1-decene, and boron to C-1. This is believed to be mainly a steric effect, but the regioselectivity of addition does conespond to Markovnikov s rule in the sense that hydrogen is the negatively polarized atom in a B—H bond and boron the positively polarized one. [Pg.251]

Figure 17.1 Hydrogen-bonding in alcohols and phenols. A weak attraction between a positively polarized OH hydrogen and a negatively polarized oxygen holds molecules together. The electrostatic potential map of methanol shows the positively polarized O-H hydrogen (blue) and the negatively polarized oxygen (red). Figure 17.1 Hydrogen-bonding in alcohols and phenols. A weak attraction between a positively polarized OH hydrogen and a negatively polarized oxygen holds molecules together. The electrostatic potential map of methanol shows the positively polarized O-H hydrogen (blue) and the negatively polarized oxygen (red).
As described in Section 9A, most chemical bonds are polar, meaning that one end is slightly negative, and the other is slightly positive. Bond polarities, in turn, tend to give a molecule a negative end and a positive end. A... [Pg.633]


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Negative polarization

Negative-positive

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