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Popilia japonica

In particular, the importance of chirality in diverse pheromone systems has been reviewed recently (Mori, 1998). For example, olive fruit flies (Bactrocera oleae) emit racemic 2 the males detect the R enantiomer, while females detect the S (Haniotakis et al., 1986). The sex pheromone of the Osaka beetle (Anomala osakana) is 4a, while the closely related Japanese beetle (Popilia japonica) uses 4b (Table 16.1). Interestingly, 4a is a powerful behavioral antagonist in P. japonica (Tumlinson et al., 1977). The hemlock looper, Lambdina fiscellaria, responds only to (5R, 1 S)-5,I I -dimethylheptadecane. The enantiomer or the R/R or S/S diastereomers do not elicit electrophysiological or behavioral responses (Li et al., 1993). Table 16.1 gives an overview of those species where proteins from the pheromone olfactory system have been identified. [Pg.484]

It is not only drugs that have to be manufactured enantiomerically pure. This simple lactone is the pheromone released by Japanese beetles (Popilia japonica) as a means of communication. The beetles, whose larvae are serious crop pests, are attracted by the pheromone, and synthetic pheromone is marketed as Japonilure to bait beetle traps. Provided the synthetic pheromone is the stereoisomer shown, with the Zdouble bond and the R configuration at the stereogenic centre, only 25 jug per trap catches thousands of beetles. You first met this compound in Chapter 32, where we pointed out that double bond stereocontrol was important since the -isomer of the pheromone is virtually useless as a bait (it retains only about 10% of the activity). Even more important is control over the configuration at the chiral centre, because the S-enantiomer of the pheromone is not only inactive in attracting the beetles, but acts as a powerful inhibitor of the R-enantiomer—even 1% S-enantiomer in a sample of pheromone destroys the activity. [Pg.1221]


See other pages where Popilia japonica is mentioned: [Pg.482]    [Pg.4]    [Pg.4]    [Pg.4]    [Pg.4]    [Pg.1104]    [Pg.482]    [Pg.4]    [Pg.4]    [Pg.4]    [Pg.4]    [Pg.1104]   
See also in sourсe #XX -- [ Pg.449 , Pg.484 ]

See also in sourсe #XX -- [ Pg.1104 ]




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