Polysulfides thermodynamic properties

Experimental methods for smdying the thermodynamic properties of the polysulfides... 

Final remark. Even with all these data, it is felt that the database of basic thermodynamic properties for the lanthanide polysulfides remains incomplete, especially for the nonstoichiometric compounds. 

Therefore, a complete description of the redox properties of sulfur and polysulfides in classical organic solvents has been obtained on the following basis only 8g and the radical anions 8 are reducible and only the dianions 8 and 8g are oxidable. The electrochemical process has been validated in DMF by comparing simulations and the experimental data in a wide range of temperatures (233 to 313 K) and scan rates (0.005 to 2.0 Vs ). It can be reasonably extended to other organic solvents. Thermodynamic and kinetic parameters have been discussed in Ref. 60. It must be noted that Paris et al. [58] describe the reduction of sulfur... 

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