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Polysilane polymers glass transition temperatures

Very recently, however, two papers were published by the group of Fujiki which report successful solid-state CD studies of chiral polysilanes. In the first, a helix-coil transition was described for film samples of poly[(A)-3,7-dimethyloctyl- -propylsilylene)], 113.327 This polymer has a relatively low glass transition temperature, T, which was considered critical for the observation of a helix-helix transition in the solid state, since helical inversion would be precluded if the inversion temperature, Tc, were below Ts as the segmental motion of the chain,... [Pg.618]


See other pages where Polysilane polymers glass transition temperatures is mentioned: [Pg.262]    [Pg.296]    [Pg.262]    [Pg.206]    [Pg.416]    [Pg.1225]    [Pg.19]    [Pg.273]    [Pg.20]    [Pg.26]    [Pg.634]    [Pg.215]    [Pg.106]   
See also in sourсe #XX -- [ Pg.1225 ]




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