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Di- and polynuclear metal carbonyl compounds have a general tendency to engage in a type of fiuxional behavior called carbonyl scrambling. This type of behavior arises because of some of the inherent properties of metal to CO bonding. As shown in Fig. 1-13, the energy of a binuclear system consisting of two metal atoms... [Pg.18]

Rearrangements in polynuclear transition metal clusters " Carbonyl scrambling and rearrangement ... [Pg.4580]

See other pages where Polynuclear carbonyls, scrambling is mentioned: [Pg.80] [Pg.76] [Pg.90] [Pg.369] [Pg.173] [Pg.226]