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Polymerization on electrodes

The mechanisms of the oxidation of solvents such as THF and PC were studied by several groups, utilizing FTIR and XPS spectroscopy [107-109] and on-line mass spectrometry (DEMS-differential, electrochemical mass spectroscopy [110-112]). For example, using ex situ FTIR spectroscopy, Lacaze et al. [46] showed that THF in FiC104 solutions are polymerized on electrodes biased to high potentials. The proposed mechanism involves oxidation of C104 as an initial step, as shown in Scheme 7 [46,102], ESR measurements also support such a mechanism. However, there are also suggestions for possible direct oxidation... [Pg.213]

Electrochemical polymerization. The electrode substrate is immersed in monomer solution and subject to electrochemical treatment. The monomers are oxidized or reduced to an activated form which polymerizes on electrode surface. [Pg.92]


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See also in sourсe #XX -- [ Pg.33 , Pg.33 ]

See also in sourсe #XX -- [ Pg.33 , Pg.33 ]




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Polymeric electrodes

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