Polymerization kinetics synthesis

Milkovich, R. In Anionic Polymerization Kinetics. Mechanisms and Synthesis ACS Symposium Series No. 166 American Chemical Society Washington, DC, 1981. 

McGrath, J. E.,editor, "Anionic Polymerization Kinetics, Mechanisms and Synthesis," ACS Symposium Series, No. 166, 1981. 

McGrath JE (ed) (1981) Anionic polymerization kinetics, mechanism and synthesis, vol 166. American Chemical Society, Washington... 

C02-philic molecules have been utilized for the design of metal-mobilizing ligands to be used in SCCO2 [67-69,135-137], e.g., as shown in Fig. 7a [55] and for the synthesis of surfactants that form micelles, emulsions, and micro emulsions in CO2, e.g., as shown in Fig. 7b. [70] Polymer solubility in SCCO2 has been studied [71] and utilized for polymer synthesis [72-74]. Recently, DeSimone and co-workers synthesized high-molar-mass fluoropolymers in SCCO2, and studied the polymerization kinetics [75]. 

Sormani PM, McGrath JE (1985) Kinetics and mechanisms of the anionic ring opening polymerization of cyclosiloxanes in the presence of bis(l,3-aminopropyl tetramethyl-disiloxane) In McGrath JE (ed) Ring opening polymerization kinetics mechanisms and synthesis. ACS Symposium Series No 286... 

Flory polymerization kinetics (4). Henrici-Olive and Olivd (5) proposed the use of the related equation of Schulz (6). Over the last decade the Flory equation has been used frequently to describe product distributions in FT synthesis. The Friedel-Anderson (i) or Flory (4) approaches apply when the rates of propagation and termination are independent of carbon number. We do not attempt here to discuss all previous research on FT product distributions except to say that the literature contains many examples of product distributions that obey Flory kinetics within relative narrow carbon number ranges and many that do not. 

Initial advances have been made in MCM synthesis and further studies are in progress [82]. It was not until recently that polymerization kinetics of such systems and properties of the resulting PCMU have received attention. Thus, radical polymerization of the dimethyl ester of hemin was carried out in 1977 [85]. The possibility of polymerizing 4-vinylpyridine (4-VP) complex-bound to Ru(II) (cis-[Ru(Dipy)2(4-VP)X]n+ complexes, where n = 1, X = Cl n = 2, X = CO or 4-VP) has been shown [86a] but the properties of the polymers obtained have... 

The F-T synthesis typically follows polymerization kinetics. The Anderson-Schulz-Flory equation describes the product distribution ... 

H. L. Hsieh, R. P. Quirk, Anionic Polymerization, Marcel Dekker, New York, 1996 J. E. McGrath, ed., Anionic Polymerization, Kinetics, Mechanisms, and Synthesis, ACS Symposium Series 166, American Chemical Society, Washington, DC, 1981 M. Morton, Anionic Polymerization Principles and Practice, Academic Press, New York, 1983. 

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