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Polymer semiconductor development copolymers

The molybdenum neopentyUdene complex Mo(CHBu )(NR)(OBu )2 is the active catalyst used in a fascinating development for the synthesis of 11-Vt semiconductor clusters (ZnS, CdS, PbS) and silver and gold nanoclusters of predictable size within microdomains in films of block copolymers prepared by ROMP. Block copolymers of norbomene and a functionalized norbomene that wiU complex with a metal-containing compound were prepared and characterized as monodisperse materials. The functionalized component (amine, alkoxide, or thiolate) then sequestered the metal and the metallated block copolymer was cast into a film which was subsequently treated with H2S to convert the metal into the sulfide. The molybdenum complexes have also featured in the development of the synthesis of side-chain liquid crystal polymers by living ROMP.98 99... [Pg.679]

See other pages where Polymer semiconductor development copolymers is mentioned: [Pg.184]    [Pg.237]    [Pg.107]    [Pg.172]    [Pg.125]    [Pg.141]    [Pg.125]    [Pg.14]    [Pg.202]    [Pg.390]    [Pg.1329]    [Pg.95]    [Pg.300]    [Pg.173]    [Pg.886]    [Pg.279]    [Pg.439]    [Pg.10]    [Pg.293]    [Pg.188]    [Pg.16]    [Pg.296]    [Pg.306]    [Pg.313]    [Pg.125]   
See also in sourсe #XX -- [ Pg.407 ]



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Polymer copolymers

Polymer semiconductor development

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