Polymer patterns, multiply

Polymer Patterns Versus Multiply Charged Ion Series... [Pg.122]

At first we have deliberately focused on the applied (technological) importance of the study of melt behavior under extension since the theoretical importance of the analysis of melt extension for polymer physics and mechanics can be regarded as already generally recognized. The scientific success and recognition of melt extension stems, we believe, from several fundamental causes, major of which are as follows. The geometrical pattern of deformation (shear, twisting, tension, etc.) is not very important for mechanics of the usual solid bodies since there is a well-known and multiply verified connection (linear Hooke s mechanics) between the main (if... [Pg.2]

Fig. 8. Generation of the form of the helical diffraction pattern. (A) shows that a continuous helical wire can be considered as a convolution of one turn of the helix and a set of points (actually three-dimensional delta-functions) aligned along the helix axis and separated axially by the pitch P. (B) shows that a discontinuous helix (i.e., a helical array of subunits) can be thought of as a product of the continuous helix in (A) and a set of horizontal density planes spaced h apart, where h is the subunit axial translation as in Fig. 7. This discontinuous set of points can then be convoluted with an atom (or a more complicated motif) to give a helical polymer. (C)-(F) represent helical objects and their computed diffraction patterns. (C) is half a turn of a helical wire. Its transform is a cross of intensity (high intensity is shown as white). (D) A full turn gives a similar cross with some substructure. A continuous helical wire has the transform of a complete helical turn, multiplied by the transform of the array of points in the middle of (A), namely, a set of planes of intensity a distance n/P apart (see Fig. 7). This means that in the transform in (E) the helix cross in (D) is only seen on the intensity planes, which are n/P apart. (F) shows the effect of making the helix in (E) discontinuous. The broken helix cross in (E) is now convoluted with the transform of the set of planes in (B), which are h apart. This transform is a set of points along the meridian of the diffraction pattern and separated by m/h. The resulting transform in (F) is therefore a series of helix crosses as in (E) but placed with their centers at the positions m/h from the pattern center. (Transforms calculated using MusLabel or FIELIX.)...

$Fig. 8. Generation of the form of the helical diffraction pattern. (A) shows that a continuous helical wire can be considered as a convolution of one turn of the helix and a set of points (actually three-dimensional delta-functions) aligned along the helix axis and separated axially by the pitch P. (B) shows that a discontinuous helix (i.e., a helical array of subunits) can be thought of as a product of the continuous helix in (A) and a set of horizontal density planes spaced h apart, where h is the subunit axial translation as in Fig. 7. This discontinuous set of points can then be convoluted with an atom (or a more complicated motif) to give a helical polymer. (C)-(F) represent helical objects and their computed diffraction patterns. (C) is half a turn of a helical wire. Its transform is a cross of intensity (high intensity is shown as white). (D) A full turn gives a similar cross with some substructure. A continuous helical wire has the transform of a complete helical turn, multiplied by the transform of the array of points in the middle of (A), namely, a set of planes of intensity a distance n/P apart (see Fig. 7). This means that in the transform in (E) the helix cross in (D) is only seen on the intensity planes, which are n/P apart. (F) shows the effect of making the helix in (E) discontinuous. The broken helix cross in (E) is now convoluted with the transform of the set of planes in (B), which are h apart. This transform is a set of points along the meridian of the diffraction pattern and separated by m/h. The resulting transform in (F) is therefore a series of helix crosses as in (E) but placed with their centers at the positions m/h from the pattern center. (Transforms calculated using MusLabel or FIELIX.)...$

When applying ESI-MS for the characterization of polymers, a high spectral resolution is beneficial. This allows the isotope pattern of multiply ionized peaks to be resolved. Even after a separation by, for example, SEC, copolymers may stiU give rise to very complex ESI-MS spectra, because many different molecules may elute at the same retention time,. ain, high-resolution MS is desirable. MS-MS is also an interesting option. [Pg.173]

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