Polyborates synthesis

PolyCy-benzyl L-glutamate) (PBLG), 15 109 Poly(y-ketosulfide)s, optically active, 23 711 Poly(P-alanine), 1 292 Poly-P-hydroxybutyrate (PHB), 12 482 Polybetaines, 20 479-482 applications of, 20 482 preparation of, 20 480-481 solution properties of, 20 481-482 synthesis of, 20 479-481 Polyborates, 4 256-258 Polyborosiloxanes, in silicon carbide manufacture and processing, 22 533 Polybrominated diphenyl ethers (PBDEs), 13 142-143 20 56... 

The effect of neutral salts (e.g., NaCl) on the composition of borates precipitated from, or in equilibrium with, aqueous solutions doubtless arises from a reduction in water activity, metal borate complexation, and a shift in polyborate equilibria (Sections IV,A, B). The "indifferent or inert component method has frequently been used for the synthesis of borates. Potassium and sodium chlorides can be used to enhance the precipitation of specific nickel (48), aluminum (51), iron (49), and magnesium (151) borates. In the K20-B203-H20 system at 25°C (248), the presence of potassium chloride results in a reduced boric acid crystallization curve, lower borate solubilities, lower pH, and an extended B203 K20 range over which the pentaborate crystallizes. 

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