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Poly organometallics

M. Zeldin, K. J. Wynne, and H. R. AUcock, eds.. Inorganic and Organometallic Poljmers, ACS Symposium Series, Vol. 360, American Chemical Society, Washington, D.C., 1988 regarding poIy(phosphazenes), poly(silanes), and other polymers. [Pg.265]

Organometallic compound Support Poly- merization temperature (°C) Normalized polymerization activity6 (g C2H4/mmole M hr atm) References... [Pg.188]

Kim KT, Vandermeulen GWM, Winnik MA, Manners I (2005) Organometallic-polypeptide block copolymers synthesis and properties of poly(ferrocenyldimethylsilane)-b-poly (gamma-benzyl-L-glutamate). Macromolecules 38 4958 961... [Pg.25]

Metal-acetylide complexes have been used as a unit of organometallic polymers that have metallic species in the main chain [20]. Representative examples are metal-poly(yne) polymers (19) of group 10 metals depicted in Scheme 5. These polymers are easily prepared from M(PR3)2Cl2 (M=Pt, Pd) and dialkynyl compounds catalyzed by Cu(I) salts in amine. Recently, this synthetic method was successfully applied to the construction of metal-acetylide dendrimers. [Pg.47]

Thus, important structure/property relationships are emerging that are relevant to electronic and optical materials applications for these materials. In a different vein, side chain crystallization has resulted in the first liquid crystalline inorganic and organometallic macromolecules, viz., unusual poly(dialkoxy-phosphazenes) described by Allcock (p. 250) and Singler (p. 268). [Pg.4]

It is well known that the mechanical and physical properties of vinyl polymers are dependent upon their stereochemical configuration. It is critical, therefore, that the stereoregularity of poly(TBTM/MMA) be determined accurately and conveniently if the field performance of the material is to be predicted with any certainty. The effectiveness of organometallic polymers as an anti-... [Pg.490]

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See also in sourсe #XX -- [ Pg.191 , Pg.192 ]



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