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Poly nucleophilic displacement polymerization reaction

Diazotization in the presence of boron trifluoride enables diazonium tetrafluoroborates to be isolated from the reaction mixture and purified. Subsequent controlled decomposition produces the required fluoroaromatic. Although explosion hazards and the toxicity of the isolated salts are significant concerns with this process, known as the Balz-Schiemann process, 4,4 -di-fluorobenzophenone (BDF. 6) has been prepared by this route as a monomer for the production of the engineering plastic poly(ether ether ketone) , or PEEK , by condensation with 1,4-dihydroxybenzene in the presence of potassium carbonate. BDF 6 is superior to its chlorine analog because in aromatic systems the nucleophilic displacement of fluorine is more facile than that of chlorine, leading to a shorter polymerization time and a better quality product containing less degradation impurities. [Pg.75]

The Ullman reaction has long been known as a method for the synthesis of aromatic ethers by the reaction of a phenol with an aromatic halide in the presence of a copper compound as a catalyst. It is a variation on the nucleophilic substitution reaction since a phenolic salt reacts with the halide. Nonactivated aromatic halides can be used in the synthesis of poly(arylene edier)s, dius providing a way of obtaining structures not available by the conventional nucleophilic route. The ease of halogen displacement was found to be the reverse of that observed for activated nucleophilic substitution reaction, that is, I > Br > Cl F. The polymerizations are conducted in benzophenone with a cuprous chloride-pyridine complex as a catalyst. Bromine compounds are the favored reactants.53,124 127 Poly(arylene ether)s have been prepared by Ullman coupling of bisphenols and... [Pg.346]

Kim et al. prepared poly(biphenylene oxide)s (PBPOl and PBP02) containing -CF3 groups from AB-type monomers [45] through nucleophilic nitro displacement reaction and investigated their properties. To investigate the feasibility of the polymerization, the model reaction was performed with... [Pg.14]


See other pages where Poly nucleophilic displacement polymerization reaction is mentioned: [Pg.239]    [Pg.283]    [Pg.158]    [Pg.7]    [Pg.389]    [Pg.534]    [Pg.210]    [Pg.274]    [Pg.276]    [Pg.70]    [Pg.286]    [Pg.65]    [Pg.271]   
See also in sourсe #XX -- [ Pg.12 ]




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Displacement polymerizations

Nucleophiles polymerization reactions

Nucleophilic displacement

Nucleophilic displacement polymerization reaction

Nucleophilic displacement reactions

Poly , polymeric

Poly displacement reaction

Poly reaction

Polymerization nucleophilic

Polymerization nucleophilic displacement

Polymerization poly

Polymerization reaction

Reaction displacement

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