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Poly melting point, molecular weight effect

Relationship Between Molecular Structure and Composition of Poly(ethylene-co-p-MS) Copolymers. From above discussion, we have shown that poly(ethylene-co-p-MS) copolymers with a wide range of compositions can be achieved by varying the p-MS monomer concentration in the feed. To fully understand the properties of this new class of materials, it is very important to know the correlation between the copolymer compositions and their molecular structures. In this section, we focus on the effect of p-MS concentration on molecular weight, molecular weight distribution, melting point (Tm), crystallinity and glass transition temperature (Tg) of the copolymer. A series of copolymers with various p-MS concentrations were analyzed by GPC and DSC. [Pg.171]


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See also in sourсe #XX -- [ Pg.147 ]




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