Polarisation photons

Let C and E represent probabilities of scattering an electron through +0 and -0, respectively, with the.emission of a left-hand circularly polarised photon in the y-direction. Correspondingly B and D are probabilities of electron scattered through +0 and -0, respectively, with a right hand circularity polarised photon in the y-direction. Four possible experiments can be considered. 

Measurements of the right-left electron scattering asymmetry in coincidence with right- (or left-) hand circularly polarised photons gives... 

The different interaction principles also explain why strongly IR-active vibrations typically exhibit weak Raman bands and vice versa, even if the selection rules would allow a vibration. If a strong dipole exists in a molecule, the electron cloud is strongly polarised. A change of polarisation in response to the electric field of a photon is therefore not very likely. 

The interaction between light and matter can be viewed as the creation of a coherent quantum superposition of initial and final electron states that has an associated polarization [3], as shown in Figure 1. The coherence between states with different wave vector requires an intermediate virtual state and the presence of a coherent phonon. A transition between the initial and final states may occur when the coherence of the system is broken either due to the finite width of an optical wave packet or by scattering from the environment. The transition results in the absorption of a photon and the creation of a hot electron-hole pair. Otherwise, the photon is re-radiated with a different phase and, perhaps, polarisation. 

Fig. 1. Feynman diagrams representing various contributions to the Lamb shift. A solid line represents an electron, a wavy line a virtual photon and a cross denotes exchange of a Coulomb photon (a) Leading self-energy term (b) One-loop vacuum polarisation term. The loop represents a virtual electron-positron pair (c) Some diagrams contributing to the two-loop binding correction...

Nafie (1992) has given a review about the latest VOA instrumentation. Until 1988, the only measured form of ROA was incident circular polarisation (ICP) ROA, but as the process observed in Raman spectroscopy is a two-photon process, there are four possibilities for measuring Raman optical activity. ICP ROA is the unpolarized measurement of the Raman radiation emitted upon excitation with alternating right and left circularly polarized light. It is shown in Fig. 6.3-12, following the sketches of Nafie. As the first of the other possibilities scattered circular polarisation (SCP) ROA was measured. This... 

Using the polarisation tensors (B.16, B.17), the free photon propagator (A.9) and the longitudinal and transverse polarisation functions /7 /r( ) the Dyson equation for reads... 

Integral cross sections for selected electron-impact excitation and ionisation processes have been largely obtained by measuring optical excitation functions. These need to be corrected to a varying degree of accuracy for effects such as cascade contributions and photon polarisation. The details of the experimental procedures, sources of errors and data evaluation have been discussed by Heddle and Keesing (1968). 

Electron—photon coincidences — angular and polarisation correlations... 

---