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Plutonium oxide reaction with, phosgene

In contrast, if plutonium(IV) oxide is prepared in an active form (by thermal decomposition of plutonium(IV) oxalate at 3(X) C [1683b,2042], or by calcination of a plutonium nitrate solution [261]), it will react with phosgene at between 350 and 400 C [2042]. Kinetic studies (between 425 and 525 C) have shown the reaction to be first order in PuOj, with an activation energy of 72.0 kJ mol [1924]. Moreover, it was demonstrated conclusively that the smaller the PuOj particles, the greater the reaction rate [1924], even... [Pg.380]


See other pages where Plutonium oxide reaction with, phosgene is mentioned: [Pg.312]    [Pg.121]    [Pg.215]    [Pg.220]    [Pg.990]    [Pg.263]    [Pg.268]    [Pg.557]    [Pg.585]    [Pg.752]    [Pg.842]    [Pg.944]    [Pg.1045]    [Pg.1127]    [Pg.1127]    [Pg.1129]    [Pg.1130]    [Pg.1131]    [Pg.1134]    [Pg.1135]    [Pg.1182]    [Pg.5550]    [Pg.220]   
See also in sourсe #XX -- [ Pg.380 ]




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Oxides reaction with, phosgene

Phosgenation reaction

Phosgene oxide

Phosgene, reaction

Plutonium oxidation

Plutonium oxidative

Plutonium oxides

Plutonium oxides reaction

Reaction with phosgene

With phosgene

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