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Platinum compounds trans influence

Platinum(IV) isocyanide complexes PtCU(CNR)2 and [PtCl2(CNR)2(PMe2Ph)2]2+ have been prepared by the addition of Cl2 to the corresponding platinum(II) compounds (equation 118).363 It is probable that the trans influence of the isocyanide ligand on platinum(IV) is greater than that of a tertiary phosphine. [Pg.380]

A study of platinum-fluorine coupling constants in compounds of the type rrarcs-Pt(PEt3)2(X)CF3 CF F2 (where F1 is trans to the metal) shows that while /(Pt-F3) correlates linearly with other measures of the trans-influence of X, /(Pt-F1) and 7(Pt-F2) do not, and reasons for this, including a through-space contribution which depends on the orientation of the C-F bond with respect to the co-ordination plane of the platinum, are discussed. (148)... [Pg.84]

Ab initio calculations on the trans effect at platinum(II) and rhodium(I) rationalize its operation in terms of the trigonal-bipyramidal reaction intermediates. Theoretical studies on some palladium(II) ethene compounds (all of them Wacker process intermediates) suggested a trans influence series OH >C1" >OH2 at this metal. ... [Pg.93]

See other pages where Platinum compounds trans influence is mentioned: [Pg.325]    [Pg.259]    [Pg.278]    [Pg.538]    [Pg.169]    [Pg.389]    [Pg.391]    [Pg.435]    [Pg.450]    [Pg.26]    [Pg.95]    [Pg.99]    [Pg.177]    [Pg.59]    [Pg.537]    [Pg.163]    [Pg.71]    [Pg.377]    [Pg.47]    [Pg.10]    [Pg.109]    [Pg.41]    [Pg.823]    [Pg.5235]    [Pg.5262]    [Pg.5264]    [Pg.5323]    [Pg.356]    [Pg.259]    [Pg.719]    [Pg.237]    [Pg.447]    [Pg.380]    [Pg.109]    [Pg.389]    [Pg.109]    [Pg.259]    [Pg.388]    [Pg.259]    [Pg.132]    [Pg.367]    [Pg.479]    [Pg.1036]    [Pg.340]    [Pg.337]    [Pg.533]   
See also in sourсe #XX -- [ Pg.126 , Pg.141 , Pg.142 ]

See also in sourсe #XX -- [ Pg.126 , Pg.141 , Pg.142 ]



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Platinum compounds

Platinum trans

Trans influence

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