Platinate tetrabutylammonium

N Oi Pt,C44H7 , Platinate(2-), hexa-p-car-bonyl-hexacarbonylhexa-bis(tetrabutylammonium), 26 316... 

PtftN2012C44H72, Platinate(2-), hexa-p,-car-bonyl-hexacarbonylhexa-bis(tetrabutylammonium), 26 316 Pt4N20]BC34H4o, Platinate(2 -), tris[tri-p.-carbonyl-tricarbonyltri-bis(tetraethylammonium), 26 322 PtijNjOjjCjuHj, Platinate(2-), tetrakis[tri-(x-carbonyl-tricarbonyltri-bis(tetraethylammonium), 26 321 Pt N203,C4(,H4 , Platinate(2-), pentakis-[tri- x-carbonyl-tricarbonyltri-bis(tetraethylammonium), 26 320... 

Deposition of platinum metal In the case of platinum no solid product was found. The ionic liquid darkened more and faster the smaller the distance between the surface of the ionic liquid [EMIM][TfO] containing tetrabutylammonium hexachloro-platinate ([n-Bu4N]2[PtCl6]) and the Ar/H2-plasma (3 1, overall pressure 100 Pa) was chosen. So far no other ionic liquid has been tested. The rate constant for the reduction of the tetrabutylammonium ion with a hydrated electron is only 1.4 x 106 LmoH1 s 1, hence the main rival pathway for reduction of platinum(IV) is the reduction of the imidazolium ion of the ionic liquid. As in the case of copper, a suitable platinum salt - maybe made by electro-oxidation of metallic platinum in a suitable ionic liquid - has to be found. 

CbNPtSCuHu, Platinate(ll), trichloro(di-methyl sulfide)-, tetrabutylammonium, 22 128... 

Oj4N2Pt 2C4(,H4o, Platinate(2-), tetrakis-[tri-p-carbonyl-tricarbonyltri-, bis-Oetraethylammonium), 26 321 026MO, NiCmHi , Octamolybdate(VI), te-trakis(butylammonium), 27 78 02iiN,V, C4 H ii, Decavanadate(V), tris-(tetrabutylammonium)trihydrogen, 27 83... 

In this synthesis tetrabutylammonium trichloro (dimethyl sulfide) platinate(II) is prepared by the reaction of di-jt-chloro-dichlorobis (dimethyl sulfide) diplatinum (II) with tetrabutylammonium chloride by a modification of the method of Goggin et al.1... 

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