Plastics toughening

Kim N H and Kim H S, Inter-particle/void distance measurement for plastics toughening. Fifth international conference on composite science and technology, American University of Sharjah, United Arab Emirates, Feb 1-3, 2005, pp. 257-262. 

Kim N H and Kim H S (2005) Inter-particle/void distance for plastic toughening, Scripta Mater 52 739-743. 

Some of the more important methods of failure studies include stress-strain, impact loading, and fatigue. Creep and stress relaxation (Chapter 10) may cause serious damage to engineering materials, but they normally do not result in fracture per se except for creep rupture. Emphasis in this chapter will be on the study of fracture energy, kinetics of crack growth, and molecular mechanisms. The reader is directed to Chapter 13 for a fuller discussion of plastic toughening. 

Plastics toughened against fracture by increasing the critical energy release rate. 

Xuedong Li. Plastic toughening rigid filler. Plastic, 24(5) 5-12, 1995. 

C. B. BucknaH, Toughened Plastics AppHed Science Pubhshers, London, 1977. 

Mechanical properties of mbber-modifted epoxy resins depend on the extent of mbber-phase separation and on the morphological features of the mbber phase. Dissolved mbber causes plastic deformation and necking at low strains, but does not result in impact toughening. The presence of mbber particles is a necessary but not sufficient condition for achieving impact resistance. Optimum properties are obtained with materials comprising both dissolved and phase-separated mbber (305). 

H. Breuer, J. Stabenow, and F. Haaf, Toughening ofP/asties, Plastics and Rubber Institute, London, 1978, Paper No. 13. 

R. Siebert, "Rubber-Modified Thermoset Resins," in C. K. Riew and J. K. GiUham, eds., ACS Advances in Chemistry Series 208, American Chemical Society, Washington, D.C., 1983, p. 179 W. D. Bascom and D. L. Hunston, "Rubber Toughened Plastic," Adv. Chem. Ser. No. 222, American Chemical Society, Washington, D.C., 1989. 

BUCKNALL, c. B., Toughened Plastics, Applied Science, London (1977)... 

Since the mid-1950s several materials have been found effective in combating ozone-initiated degradation, in particular certain p-phenylenediamine derivatives. The actual choice of such antiozonants depends on the type of polymer and on whether or not the polymer is to be subject to dynamic stressing in service. Since antiozonants are not known to have any use in plastics materials, even those which may have certain rubber particles for toughening, they will not be dealt with further here. Anyone interested further should consult references 3-5. 

Urethane structural adhesives have a morphology that is inverse to the toughened epoxy just described. The urethanes have a rubber continuous phase, with glass transition temperatures of approximately —50°C. This phase is referred to as the .soft segment . Often, a discontinuous plastic phase forms within the soft segment, and that plastic phase may even be partially crystalline. This is referred to as the hard segment . A representation of the morphology is shown in Fig. 3 [34]. 

Heterogeneous compatible blends of preformed elastomers and brittle plastics are also an important route for the development of blends of enhanced performance with respect to crack or impact resistance. Polycarbonate blends with preformed rubber particles of different sizes have been used to provide an insight into the impact properties and the fracture modes of these toughened materials. Izod impact strength of the blends having 5-7.5 wt% of rubber particles exhibits best overall product performance over a wide range temperature (RT to -40°C) [151-154]. 

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