Pigments injection molding

The major uses of aniline are in the manufacture of polymers, mbber, agricultural chemicals, dyes and pigments, pharmaceuticals, and photographic chemicals. Approximately 67% of the wodd production of aniline is used in the manufacture of rigid polyurethanes and reaction-injection-molded (RIM) parts for the constmction, automotive, and durable goods industries. 

Pellets for injection-molding, extmsion, and blow-molding appHcations include mineral-filled, glass-filled, pigmented, and flame-retarded grades. 

In the case of polyolefins the dispersing performance of single-screw extruders and injection molding machines is not sufficiently to undertake high-quality coloration (fibers, film, tape) with powder pigments or pigment mixtures. 

A number of organic pigments can cause warping of certain thick-walled, large-area, non-axially symmetrical injection-molded parts such as bottle crates, where they act as nucleating agents for partially crystalline polymers. 

Pigment powders continue to be used in thick-walled articles, such as extruded sheets, or hollow objects, or in injection-molded products although color concentrates are beginning to be more important even in these areas. 

Thermosets are processed by compression molding, transfer molding and injection molding or by extrusion, depending on their structure. The pressing temperatures are about 150 to 190°C. Corresponding requirements are placed on the pigments. Dyes are often also used to color thermosets. 

More than 0.3% pigment is required to formulate 1/3 SD HDPE samples. P.Gr.36 is thus much weaker than P.Gr.7 types, although it withstands more than 300°C and is thus equally heat stable. Considerable influence on the shrinkage of injection-molded polyethylene parts necessitates some caution in using P.Gr.36 for this purpose. Many types are difficult to disperse in plastics, especially in polyolefins. 

Transparent and reduced 1/3 SD polyolefin systems are stable up to 300 to 320°C. 0.25% pigment is required in order to formulate 1/3 SD HDPE samples containing 1% TiOz. P.O.43, incorporated in injection-molded partially crystalline plastics such as HDPE, affects the shrinkage of the medium, which precludes its use in nonrotation symmetrical injection-molded articles (Sec. 1.6.4.3). 

Transparent polyolefin systems containing P.R.88 are stable up to 260 to 300°C, depending on the type and on the pigment content. 1/3 SD systems are heat stable up to approximately 240 to 260°C. Some types are recommended only for use in LDPE at low processing temperatures. The lightfastness of such specimens is between step 6 and step 7 on the Blue Scale. P.R.88 considerably affects the shrinkage of injection-molded articles, a feature which somewhat restricts its application in such systems. 

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