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Photoreactive nanomatrix graft copolymerization

Photoreactive Nanomatrix Structures Formed by Graft Copolymerization of 1,9-Nonanediol Dimethacrylate onto Natural Rubber... [Pg.344]

Photoreactive nanomatrix structures are novel functional nano-phase separated structures obtained by graft copolymerization, which consist of a dis-persoid of major elastomer and a matrix of minor functional polymer having carbon-carbon double bonds as a photoreactive site. The photoreaction of the polymer in the nanomatrix may cement the nanomatrix structure with not only crosslinking junctions of the elastomer in the dispersoid and chemical linkages... [Pg.344]

Photoreactive Nanomatrix Structures Formed by Graft Copolymerization... [Pg.345]

The photoreactive nanomatrix structure was formed by graft copolymerization of the inclusion complex of NDMA with p-CD onto deproteinized natural rubber. The content, conversion and residual methacryloyl group of NDMA for the graft copolymerization were 1.81%, 58.5% and 45.3%, respectively, at NDMA feed of 150 g/kg rubber and initiator concentration of 0.033 mol/kg rubber. The TEM observation of the resulting graft copolymer showed that natural rubber particles of about 1.0 pm in diameter were dispersed in a poly(NDMA) matrix of 10 nm in thickness. [Pg.354]

See other pages where Photoreactive nanomatrix graft copolymerization is mentioned: [Pg.345]    [Pg.354]   
See also in sourсe #XX -- [ Pg.330 , Pg.331 , Pg.332 , Pg.333 ]



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