Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Photon absorption processes

In a two-photon absorption process the first photon takes the molecule from the initial state 1 to a virtual state V and the second takes it from V to 2. As in Raman spectroscopy, the state V is not an eigenstate of the molecule. The two photons absorbed may be of equal or unequal energies, as shown in Figures 9.27(b) and 9.27(c). It is possible that more than two photons may be absorbed in going from state 1 to 2. Figure 9.27(d) illustrates three-photon absorption. [Pg.371]

There are various approximations (7) to the above expression for the absorption rate Rj that offer further insight into the photon absorption process and form a basis for comparison to the non Bom-Oppenheimer rate expression. The most classical (and hence, least quantum) approximation is to ignore the fact that the kinetic energy operator T does not commute with the potentials Vj f and thus to write... [Pg.298]

The intensity of the upconverted beam as a function of the intensity of the exciting radiation for Er3+ doped into CeC>2 is given in the following table. Determine whether the up-conversion is likely to be a two- or three-photon absorption process. [Pg.445]

Its value can lie anywhere in the range 10-6 to 106. A value of 10-6 implies that the photon absorption process is very inefficient, with only one molecule absorbed per million photons. In other words, the energetic requirements for reaction are not being met. [Pg.452]

The total fluorescence intensity saturated around a few hundreds of mJ/cm2 which corresponds to the irradiation condition where the new plasma-like emission was observed. Above this value fluorescence intensity decreased, which is accompanied with the recovery of the relative intensity of excimer emissions. This means that a quite efficient deactivation channel of excitation intensity opens in this energy range, and the contribution of Si -Si annihilation is depressed. This suggests that fragmentation reactions to diatomic radicals are not induced by the annihilation process. Multi-photon absorption processes via the Si states and chemical intermediates should be involved, although no direct experimental result has as yet been obtained. [Pg.405]

The population of level 2 occurs after a two-step, two-photon absorption process. The first step populates level 1 and the second step populates level 3, which feeds the emitting level 2. [Pg.24]

Baldeck and Andraud provide a chapter entitled Exitonic Coupled Oligomers and Dendrimers for Two-Photon Absorption, wherein the concepts of exci-tonic coupling are developed and their relevance to multi-photon absorption processes are described. [Pg.219]

Let us formulate the various photon absorption processes in chemical shorthand as follows... [Pg.325]

Instead, Kroger ct al. suggest consecutive two-photon absorption process, that is, process (VII-134) followed by... [Pg.91]

This rule is analogous for any number of photons thus, in a three-photon absorption process the allowed states are the p and f states, which allows even-to-odd or odd-to-even parity. This means that transitions can be divided between states of either the same or different parity corresponding to absorption of either even or odd numbers of photons. Hence the selection rules are the same for one and three photons and for two and four photons, respectively [49]. [Pg.165]

The structure-property relationships are affected by three main structural elements-coordination and hence packing, which determines some of the nonlinear harmonics the degree of conjugation along the backbone and the effects of the substituents-all of which have previously been reported to affect two-photon absorption processes thus it is proposed that the same applies for other higher-order systems. However, it is rare for reports of these high-order multiphoton absorption processes displayed by organic metal complexes to be accompanied with detailed molecular structure to show the correlation between the photoproperties. [Pg.170]

An additional class of nonlinear optical effects is that of multi-photon absorption processes. Using these process, one can create excited states (and, therefore, their associated physical and chemical properties) with a high degree of three-dimensional (3D) spatial confinement, at depth in absorbing media. There are potential applications of multi-photon absorbing materials in 3D fluorescence imaging, photodynamic therapy, nonlinear optical transmission and 3D microfabrication. [Pg.393]

Finally, we note that 2 PA, and more generally simultaneous multi-photon absorption processes, has been used as a mechanism for pumping organic lasers using light available from semiconductor lasers [197-203]. [Pg.430]

As large intensities are necessary to induce a nonlinear refractive index change, not only linear but also multiple photon absorption processes have to be considered. The intensity I and the induced nonlinear phase shift NL are coupled differential equations as a function of the propagation direction z. [Pg.137]

Fig. 1a-c. Absorption and nonlinear phase shift as a function of the propagation distance for a dominating a one-, b two-, and c three-photon absorption process. The dashed line indicates the nonlinear phase shift without any absorption... [Pg.139]

In the field of optical limiting based on two-photon absorption there exists some confusion with the convention of different physical processes. We refer here to the two-photon absorption process based on a2 OC -to,to,-to,to) and... [Pg.152]

Fig. 11. Schematic of the excellent three-dimensional spatial resolution of the two-photon absorption process... Fig. 11. Schematic of the excellent three-dimensional spatial resolution of the two-photon absorption process...
The calculations were performed using the Hedin-Lundquist exchange correlation potential. When X-ray absorption spectra are calculated, a core-hole has to be present in order to mimic the photon absorption process. The calculations were performed both with and without complete core-hole screening. The optimal geometry for the clusters as derived from the ADF calculations was used as input for the FEFF8 calculations. [Pg.147]

To understand why control over the total cross section is lost and how the backward-forward symmetry is broken, we analyze in some detail the simplest case in this class, namely the interference between a one-photon and a two-photon absorption process [78], Consider irradiating a molecule by a field composed of two modes, o>2 and a)h with a)2 = 2coh for which the light-matter interaction is... [Pg.58]


See other pages where Photon absorption processes is mentioned: [Pg.422]    [Pg.161]    [Pg.141]    [Pg.385]    [Pg.86]    [Pg.403]    [Pg.189]    [Pg.202]    [Pg.82]    [Pg.2]    [Pg.3]    [Pg.271]    [Pg.36]    [Pg.356]    [Pg.158]    [Pg.91]    [Pg.158]    [Pg.175]    [Pg.196]    [Pg.168]    [Pg.169]    [Pg.134]    [Pg.152]    [Pg.153]    [Pg.522]    [Pg.174]    [Pg.301]    [Pg.55]    [Pg.157]   
See also in sourсe #XX -- [ Pg.333 ]




SEARCH



Absorption processes

Photon absorption

Photonics process

Photons process

© 2024 chempedia.info